For the folks worried about copper toxicity due to applying copper fungicide, here's what I found:
Recommended rates of copper application (as a soil nutrient) are about 3 - 6 pounds per acre (up to 18 pounds when used as a fungicide) per year. However, copper soap (copper octanoate) contains 0.15 pounds of copper per gallon of concentrate (
http://msue.anr.msu.edu/news/copper_formulations_for_fruit_crops). One gallon of copper soap concentrate is enough to treat my 1/2 acre orchard for roughly one year. So, at that rate, I'm actually under applying even for the purposes of a soil nutrient :-). I do have some symptoms of copper deficiency on selected trees (ie, gummosis).
As for the human toxicity issues, copper soap is allowed for use in organic production of vegetables right up to the day of harvest per the label :-).
So, I think the product can be used with impunity. Sulfur's story is similar. Don't let fungus ruin your mango crops !