Yep, I think neem oil is effective against soft scale. Hard scale (eg, lobate lac) seems to be more of a challenge.
I definitely wouldn't use sevin :-). That's like using a stick of dynamite to kill a fly. All of your beneficials will go belly-up. Its great if you need a sterile soil medium (for shipping across state lines for example), but not so great if you like worms, millipedes, etc.
AzaSol and BotaniGard have worked well for me, and neither product contains oil, so there is no risk of burning. The only drawback (beside cost of course) is that both products degrade pretty quickly. AzaSol has a lifespan if about 2 years, botanigard 6 months to a year.
And with the above in mind -- neem oil's active ingredient (azadirachtin) can degrade fairly quickly, especially if stored in a hot garage. You should store them in a a/c controlled environment.