Here we

use chlorpyrifos in a powdered form, which doesn't work very well. You powder their entrances and lines, and hope for the best. I even get on hands and knees and blow some of the powder down the entrance. Inevitably in a week or so, they will be back, rinse and repeat for weeks on end.
A biological agent would work better.
Edit: Here's a nice article from Brazil where scientists conducted an experiment with some sort of processed orange pulp as a carrier bait into which they infused sulfluramid at 0.3% concentration. Apparently the ants incorporated more of the sulfluramid pellets into their nest than even the control group (the processed orange pulp without any insecticide). That might have just been a coincidence, but the mechanism of action sounds very convincing to me.
The sulfluramid is very slow acting, so the worker ants don't perceive the compound. The ants feed this bait to their fungus and only after the bait has been incorporated into the fungus, does the sulfluramid start to affect the worker ants. The workers are not able to associate the bait as being the source of toxicity as they are able to do with more acute toxins from their environment. The article states that after three or four days the ants stop harvesting plant material from the landscape, and all individuals die 16-22 days following the treatment.
https://www.sciencedirect.com/science/article/pii/S0085562619300755Sounds promising to me. Now I just have to see if I can find a product with this chemical composition.