I am far from an expert on this, but it was explained to me that since the cambium is the layer of cells between the bark and the "wood" when you peel back the bark for the graft, the majority of the exposed surface is cambium. that tissue will be able to make contact and fuse with the thin line of cambium tissue that is exposed on the scion.
In fact I know people that say you should scrape off all the bark from the "backside" of the scion so that the exposed cambial layer can make contact and fuse with the cambial tissue that remains on the inside of the bark of the rootstock. I do not know if it really helps, but there is some logic to that particular procedure.
Good Luck,
Richard